Affiliations: [a] Department of Orthodontics, Sree Anjaneya Institute of Dental Sciences, Calicut, India | [b] Department of Orthodontics, Amrita School of Dentistry, Kochi, India | [c] Technocommercial Innovation Center, English Indian Clay limited, Trivandrum, India
Correspondence:
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Corresponding author: P. Anuradha, Department of Orthodontics, Sree Anjaneya Institute of Dental Sciences, Calicut 673315, India. Tel.: +91-9446474362; E-mail: [email protected].
Abstract: The present research was aimed at developing surface coatings on NiTi archwires capable of protection against nickel release and to investigate the stability, mechanical performance and prevention of nickel release of titanium sputter coated NiTi arch wires. Coated and uncoated specimens immersed in artificial saliva were subjected to critical evaluation of parameters such as surface analysis, mechanical testing, element release, friction coefficient and adhesion of the coating. Titanium coatings exhibited high reliability on exposure even for a prolonged period of 30 days in artificial saliva. The coatings were found to be relatively stable on linear scratch test with reduced frictional coefficient compared to uncoated samples. Titanium sputtering adhered well with the Ni–Ti substrates at the molecular level, this was further confirmed by Inductive coupled plasma emission spectroscopy (ICPE) analysis which showed no dissolution of nickel in the artificial saliva. Titanium sputter coatings seem to be promising for nickel sensitive patients. The study confirmed the superior nature of the coating, evident as reduced surface roughness, friction coefficient, good adhesion and minimal hardness and elastic modulus variations in artificial saliva over a given time period.
Keywords: NiTi alloy, Ni allergy, sputtering, titanium, nanoindentation
