Linear viscoelastic model of a maturing gelatin solution

Article type: Research Article

Authors: Braidot, Ariel A.A. | Deiber, Julio A.^;

Affiliations: INTEC (UNL–CONICET), Güemes 3450, 3000 Santa Fe, Argentina

Note: [] Reprint requests to: Dr Julio A. Deiber, INTEC (UNL–CONICET), Güemes 3450, 3000 Santa Fe, Argentina. Fax: 054 342 4550944; E‐mail: treoflu@ arcride.edu.ar.

Abstract: The linear viscoelastic model proposed in this work considers the viscoelastic nature of maturing gelatin solutions through a relaxation modulus that depends on temperature and maturation. This modulus is defined in the conceptual contexts of the classical rubber elasticity theory and the rheometric gel theory. An analysis of the relationship between the equilibrium elastic modulus and the percolation variable around the gel point is also included yielding a percolation exponent close to 1.7 as expected from previous theoretical predictions. Additionally, a simple kinetic model is proposed to follow the microstructural changes obtained as a consequence of the generation of junction zones, the number of which vary with time during the dynamic rheometric tests used in this work. Thus, the storage and loss moduli are measured at different temperatures and frequencies, during the period of gelatin maturation. The theoretical aspects of the rheological model are presented emphasizing the quantitative changes of rheological parameters with the maturation.

Keywords: Gel linear viscoelasticity, gelation kinetics, gelatin maturation, percolation parameters

Journal: Biorheology, vol. 36, no. 3, pp. 267-284, 1999