Affiliations: [a] College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, P.R. China | [b] Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, P.R. China
Correspondence:
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Corresponding author: Feng Ying Bai, College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850#, Dalian 116029, P. R. China. E-mail: [email protected].
Note: [1] The authors: Miss Yu Qiao and Miss Chen Wang contributed equally to this work.
Abstract: Metal-organic frameworks [Co(Hbidc)(H2O)2] (1) and [Mn(Hbidc)(H2O)] (2), with multidentate 1H-benzimidazole-5,6-dicarboxylic acid (H3bidc) ligand, have been synthesized under hydro/solvothermal conditions and structurally characterized by elemental analysis, IR spectrum, and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that the center Co atom of complex 1 is six-coordinated with three-dimensional supramolecular structure and center Mn of complex 2 is five-coordinated with exhibiting a 2D layered network. The photodegradation of Crystal violet dye and Methylene blue dye were studied firstly by complexes 1 and 2 as photocatalysts. Research result indicates that the degradation rate for complex 1 can reach 89.85% , 90.6% and that for complex 2 can reach 88.28% , 79.48%. At the same time, corresponding to photocatalytic kinetics was performed.
