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Article type: Research Article
Authors: Yanagihara, Naohisa | Tanikawa, Shigeru | Suzuki, Nobuyuki | Rivera, Mario | Ogura, Tetsuya
Affiliations: Department of Materials Science and Engineering, Teikyo University, 1-1 Toyosatodai, Utsunomiya 320, Japan | Departamento de Quimica, ICET, Universidad Autonoma de Guadalajara, Lomas del Valle, No. 1201, Ciudad Universitaria, A.P. 1-440, Guadalajara, Jalisco, Mexico
Note: [] Author to whom correspondences should be addressed.
Note: [] Present address: Department of Chemistry, Oklahoma, State University, Stillwater, OK 74078.
Abstract: Reaction of copper(II) p-toluenesulfonate with tetrahydrothiophene (THT) forms a THT cation radical and a THT dication by stepwise one-electron oxidation by Cu2+. Generation of a dimeric species of THT dication is proposed to explain the formation of tetramethylene sulfoxide (TMSO) upon hydrolysis of the dimeric THT dication with H2O.
DOI: 10.1080/10241229712331341304
Journal: Main Group Chemistry, vol. 2, no. 2, pp. 161-163, 1997
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