Synthesis, structures and properties of Cd(II) supramolecular compound based on nitrogen heterocyclic cation

Article type: Research Article

Authors: Liu, Xin-Jing | Qiao, Xiu-Ying | Niu, Yun-Yin^{; *}

Affiliations: College of Chemistry and Molecular Engineering, Zhengzhou University, Henan, P. R. China

Correspondence: [*] Corresponding author: Yun-Yin Niu, College of Chemistry, Zhengzhou University, Henan 450052, P. R. China. E-mail: [email protected].

Abstract: A novel supramolecular compound {(L1) [CdI4]} (L1 = 1-(3-(((1 s,3R,5S)-1,3,5,7,tetraazaadamantan-1-ium-1-yl)methyl)benzyl)-1,3,5,7,-tetraazaadamantan-1-ium) was synthesized from CdI2 and L1 by self-assembly reaction in solution. Its structure was analyzed by X-ray diffraction, and X-ray crystallography showed that the crystal was mononuclear. The compound was characterized by UV, TG, photocatalysis and adsorption.

Keywords: Supramolecular polymer, photocatalytic, nitrogen heterocyclic organic cationic template

DOI: 10.3233/MGC-190892

Journal: Main Group Chemistry, vol. 19, no. 3, pp. 199-206, 2020