Solvo-thermal synthesis of an ultra-stable 3D luminescent cadmium (II) hybrid and its application as a recyclable luminescent sensor for Fe (III)

Article type: Research Article

Authors: Zhu, Gai-Hong^{; *} | Wang, Fu-Rong | Wang, Wen-Xiao | Liu, Xin-Jing

Affiliations: College of Chemistry and Molecular Engineering, Zhengzhou University, Henan, P. R. China

Correspondence: [*] Corresponding author: Gai-Hong Zhu, College of Chemistry and Molecular Engineering, Zhengzhou University, Henan 450001, P. R. China. Tel.: +86 371 67767627; E-mail: [email protected].

Abstract: A 3D imidazole-bearing cyclophane cage L1 was synthesized as trivalent cationic templates to react with metal halide to obtain a novel organic-inorganic crystalline hybrid: {[CdI4]3·(L1)2} (1). Its crystals have been grown by slow evaporation method and characterized by single-crystal X-ray diffraction analyses, infrared spectra (IR) and powder X-ray diffraction (PXRD). More importantly, the fluorescence property in solid state was studied and found the quenching efficiency is good and it can be used as a recyclable luminescence sensor for Fe3+ ions with high selectivity and stability.

Keywords: Trivalent cyclophane cages, organic and inorganic hybrids, fluorescence properties

DOI: 10.3233/MGC-190866

Journal: Main Group Chemistry, vol. 19, no. 2, pp. 125-138, 2020