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Article type: Research Article
Authors: Jeevaraj, A. Kingson Solomon | Sankar, U.
Affiliations: Department of Physics, Karunya University, Coimbatore, Tamilnadu, India | Department of Physics, AKGS Arts College, Srivaikuntam, Tamilnadu, India
Note: [] Corresponding author: A. Kingson Solomon Jeevaraj, Asistant Professor (S.G), Department of Physics, Karunya University, Coimbatore-641114, Tamilnadu. Tel.: +91 9842466973; +91 9443670199; E-mails: [email protected] (A. Kingson Solomon Jeevaraj); [email protected] (U.Sankar).
Abstract: Solute – Solvent interactions of Triethylamine (TEA) and 1-Dodecanol binary mixture have been carried out for 11 concentrations at different temperatures using LCR(Inductance (L), Capacitance (C) and Resistance (R)) meter at a frequency of 1 KHz. The Kirkwood correlation factors and excess dielectric properties were determined and discussed to give information about the molecular interactions of the systems. The static dielectric constants for the mixture have been fitted with the modified Bruggeman model. The excess permittivities are found to be positive for all concentrations and temperatures, which represent solute and solvent interact in such a way the effective dipole moment increases.
Keywords: Solute – solvent interactions, kirkwood correlation factor, modified Bruggeman model, excess permittivitiy, dielectric constants
DOI: 10.3233/MGC-130105
Journal: Main Group Chemistry, vol. 12, no. 3, pp. 251-256, 2013
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