Searching for just a few words should be enough to get started. If you need to make more complex queries, use the tips below to guide you.
Article type: Research Article
Authors: Cea-Olivares, Raymundo | Estrada, Mirna R. | Espinosa-Pérez, Georgina | Haiduc, Ionel | García, Patricia García Y | López-Cardoso, Marcela | López-Vaca, Moisés | Cotero-Villegas, Ave-María
Affiliations: Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510, D.F., MÉXICO | Facultad de Ciencias Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Chamilpa, Cuernavaca, Morelos, MÉXICO
Note: [] Corresponding author, e-mail: [email protected]
Abstract: 1-oxa-4,6-dithia-5-arsocane morpholinyldithiocarbamate (1) and 1,3,6-trithia-2-arsocane 2-diethyldithiocarbamate (2) have been prepared by reacting the corresponding sodium dithiocarbamates with 1-oxa-4,6-dithia-5-arsocane or 1,3,6-trithia-2-arsocane. (1) and (2) were characterized by elemental analyses, IR, MS, 1H and 13C NMR. The X-ray single-crystal molecular structures of (1) [monoclinic, a = 9.931 (5), b = 18.253(5), c = 8.076(3) Å; β = 92.56(2)°; V = 1462.5(7) Å3; space group P21/c; Z = 4; R = 4.33%] and (2) [monoclinic, a = 7.830(2), b = 10.465(2), c = 19.025(6) Å; β = 95.82(2)°; V = 1550.8(10) Å3; space group P21 / c; Z = 4; R = 3.41%], show that the compounds are monomeric and contain an asymmetric monometallic biconnective dithiocarbamate ligand with a large distortion in the geometry around the As and a weak heterocyclic arsocane transannular secondary interaction.
DOI: 10.1080/13583149512331338365
Journal: Main Group Chemistry, vol. 1, no. 1, pp. 159-164, 1995
IOS Press, Inc.
6751 Tepper Drive
Clifton, VA 20124
USA
Tel: +1 703 830 6300
Fax: +1 703 830 2300
[email protected]
For editorial issues, like the status of your submitted paper or proposals, write to [email protected]
IOS Press
Nieuwe Hemweg 6B
1013 BG Amsterdam
The Netherlands
Tel: +31 20 688 3355
Fax: +31 20 687 0091
[email protected]
For editorial issues, permissions, book requests, submissions and proceedings, contact the Amsterdam office [email protected]
Inspirees International (China Office)
Ciyunsi Beili 207(CapitaLand), Bld 1, 7-901
100025, Beijing
China
Free service line: 400 661 8717
Fax: +86 10 8446 7947
[email protected]
For editorial issues, like the status of your submitted paper or proposals, write to [email protected]
如果您在出版方面需要帮助或有任何建, 件至: [email protected]