Abstract: Water samples collected from early March 2001 to the end of April
2002 at the branch of Pearl River around the Guangzhou City were analyzed for
its micro-polluted characteristics. The coagulation behavior of polyaluminum
chlorides (PACls) was then examined focusing on the effect of primary water
quality and speciation distribution. The results showed that PACls exhibit
better coagulation efficiency than alum in accordance with the different
speciation.The turbidity removal property of PACls is evidently better than
alum at Iow dosage. While in neutral zone (about 6.5–7.5), the turbidity
removal of PACls decreases owing to the restabilization of particles at higher
dosage. The organic matters in raw water exhibit marked influence on
coagulation. In acidic zone, organic matters complex with polymer species and
promote the formation of flocs. With an increase in pH, the complexation of
organics with polymer species gradually decreases, and the removal of organics
mainly depends on adsorption. The effect is evidently improved with the raise
of B value.
Keywords: PACl, micro-polluted river water, DOC, coagulation efficiency