Affiliations: Department of Environmental Science and Engineering,
College of Chemical Engineering, Zhejiang University, Hangzhou 310027,China.
E-mail: lclei@mail. hz. zj. cn
Note: [] Corresponding author
Abstract: This paper describes the application of wet air oxidation to the
treatment of desizing wastewater from two textile companies. A two-liter high
temperature, high pressure autoclave reactor was used in the study. The range
of operating temperatures examined was between 150 and 290°C, and the
partial pressure of oxygen ranged from 0. 375 to 2.25 MPa. Variations in pH,
COD_Cr and TOD content were monitored during each experiment and used to assess
the extent of conversion of the process. The effects of temperature, pressure
and reaction time were explored extensively. More than 90 % COD_Cr reduction
and 80 % TOC removal have been obtained. The results have also been
demonstrated that WAO is a suitable pre-treatment methods due to improvement of
the BOD_5/COD_Cr ratio of desizing wastewater. The reaction kinetics of wet air
oxidation of desizing wastewater has been proved to be two steps, a fast
reaction followed by a slow reaction stage.
Keywords: wet air oxidation, wastewater treatment, textile wastewater