Hybrid supramolecule of azolium-linked cyclophane: Synthesis, structure and thermostability

Article type: Research Article

Authors: Li, Yuan-Yuau^{; *} | Wang, Fu-Rang | Qiao, Xiu-Yin | Huang, Wen-Min

Affiliations: College of Chemistry and Molecular Engineering, Zhengzhou University, Henan, P.R. China

Correspondence: [*] Corresponding author: Yuanyuau li, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P.R. China. E-mail: [email protected].

Abstract: In this paper, one 3D imidazole cyclophane trivalent cation was chosen with the aim of studying conformational behavior. One novel organic-inorganic hybrid supramolecule {L1·(NH4) [Mo8O26]·(H2O)} (1), has been synthesized through the self-assembly reaction. Compound 1 has been expressly confirmed by PXRD, IR, X-ray single crystal diffraction, and TG. Crystallographic analysis shows that the anion of compound 1 is Multi-core structure. TG shows that the stability of compound 1 is relatively good.

Keywords: Azolium-linked cyclophane, hybrid supramolecule, conformation behavior

DOI: 10.3233/MGC-190872

Journal: Main Group Chemistry, vol. 19, no. 2, pp. 149-156, 2020