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Article type: Research Article
Authors: Kenawy, El-Refaie | El-Shanshoury, Abd El-Raheem R.; | Omar Shaker, Nihal | El-Sadek, Baheya Mohamed | Khattab, Abeer H.B. | Elzatahry, Ahmed;
Affiliations: Department of Chemistry, Polymer Research Group, Faculty of Science, Tanta University, Tanta, Egypt | Department of Botany, Bacteriology Research Unit, Faculty of Science, Tanta University, Tanta, Egypt | Department of Biotechnology, Faculty of Science, Taif University, Taif, Kingdom of Saudi Arabia | Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt | Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia | Advanced Technology and New Materials Research Institute, City of Scientific Research and Technology Applications, New Borg El Arab City, Alexandria, Egypt
Note: [] Corresponding author: El-Refaie Kenawy, Department of Chemistry, Polymer Research Group, Faculty of Science, Tanta University, Tanta 31527, Egypt. E-mail: [email protected]
Abstract: In the present work new biocidal polymers were synthesized based on linear poly(hydroxy styrene) and poly(hydroxy styrene co-2-hydroxyethyl methacrylate). The polymer and the copolymer were modified by chloroacetylation with chloroacetyl chloride and were further modified by quaternization with triethylamine, triphenylphosphine, and tributylphosphine. The modified polymers, and copolymers were characterized by elemental analyses, IR, and 1H-NMR. The biocidal activities of the compounds were evaluated against E. coli, Staph. aureus, P. aeruginosa, Serratia sp, Kelbsiella sp. and C. albicans. The modified polymers and copolymers had biocidal activity. The toxicity analysis of the most active polymers or co-polymers to Artemia salina was also determined. It differed according to the polymer or co-polymer and its concentration.
Keywords: Biocidal polymers, Artemia salina, Poly(hydroxy styrene), quaternary ammonium and phosphonium salts
DOI: 10.3233/MGC-130109
Journal: Main Group Chemistry, vol. 12, no. 4, pp. 293-306, 2013
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