Affiliations: [a] Theoretical Physics Department, Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia | [b] Department of Physical Electronics, Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia | [c] Department of Physics, Saint Petersburg State Chemical Pharmaceutical University, St. Petersburg, Russia
Correspondence:
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Corresponding author: Elena V. Orlenko, Theoretical Physics Department, Peter the Great St. Petersburg Polytechnic University, Polytechnicheskaya St. 29, 195251, St. Petersburg, Russia. E-mail: [email protected].
Abstract: We consider an adiabatic potential of a Hydrogen-Helium interaction by using a new approach based on the exchange perturbation theory (EPT). This method allows to present results analytically. We find the solution as an expansion in an antisymmetric basis thanks to the proved completeness property for a nonorthogonal set of antisymmetric wave functions. We use the developed invariant form with respect to interatomic electron permutations for both the Hamiltonian describing an unperturbed system and the perturbation operator. The invariant form for both operators allows one to obtain properly antisymmetric corrections to the antisymmetric wave function of the zero approximation. The probability of electron scattering with electron capture by the helium atom is discussed. We use an EPT formalism developed for the time-dependent perturbations. A formalism of the Time-dependent EPT has a form of an invariant perturbation theory that accounts for intercentre electron permutations among the overlapping states. The expressions for the matrix elements of an S-matrix and a T-matrix account for interatomic electron permutations. We use the obtained differential cross section formulas for the description of the electron capture during the scattering processes. The differential cross section of the electron capture by Helium atom has a complex shape of peak for the scattering energy around 0.7 atomic units, associated with the adiabatic creation of the negative ion He(-1).
Keywords: Intercentre electron exchange, nonorthogonal basis of the antisymmetrized wave vectors, stationary case, case of degeneracy and time dependent case of the exchange perturbation theory, Helium-Hydrogen adiabatic potential, electron-Helium collision, electron capture
